![]() ![]() It was believed that on the last night of october, the spirits of the dead roamed the earth. Cute unicorn coloring pages are a fun way for kids of all ages to develop creativity, focus, motor skills and color recognition. Source: Kawaii cupcake unicorn coloring sheet. Cute unicorns coloring pages are a fun way for kids of all ages to develop creativity focus motor skills and color recognition. Source: There lies a cute adorable little girl holding a baby unicorn in her arms. Choose a coloring page that best fits you and your kids. Source: Ĭute unicorns coloring pages are a fun way for kids of all ages to develop creativity, focus, motor skills and color recognition. Your child can fill a variety of hues in the stripes across the dress. Here you can find coloring pages from games, cartoons, animated movies and fantasy world. Are you looking for unblocked games? Source: Source: I love unicorns colouring printable with pegasus. For boys and girls, kids and adults, teenagers and toddlers, preschoolers and older kids at school. Our online collection of easy and adult coloring pages feature the best pictures for you to color. ![]() For a long time, a horse with one horn was considered a symbol of nobility, strength and wisdom. Source: Ĭute unicorn coloring pages is a collection of pictures of wonderful magical creatures adored by children all over the world. The holiday is also called all hallows’ eve. Source: Download and print free cute unicorn coloring pages. The girl is standing on the cloud among the stars. Source: Coloring pages adult colouring therapy could improve your. 40 cute unicorn coloring pages for kids put together in a bumper printable unicorn coloring book. Source: The girl is standing on the cloud among the stars. Download and print free cute unicorn coloring pages. ![]() Print and color unicorns pdf coloring books from primarygames. Source: Unicorn coloring pages are a magical way to keep kids busy and adults happy. is a super fun for all ages: It was believed that on the last night of october, the spirits of the dead roamed the earth. The unicorn is a legendary animal that looks like a horse or a goat with a single horn on its forehead. These fun and educational free unicorn coloring pages to print will allow children to travel to a fantasy land full of wonders, while learning about this magical creature. This page features this year's top 10 cute unicorn coloring pages for kids. Source: Ĭute unicorn cat coloring pages.download and print free cute little cat. Unicorn cat coloring pages animal page for kids tont cute adults kawaii fox free. Unicorn colouring sheet with cattle and rainbow, perfect for. Source: These colouring pages are perfect for kids of all ages. Source: įor boys and girls, kids and adults, teenagers and toddlers, preschoolers and older kids at school. In ancient times, the holiday was marked by customs started by pagans. Source: Little girl with cute unicorn and cloud kawaii. These colouring pages are perfect for kids of all ages. Unicorn coloring pages are a magical way to keep kids busy and adults happy. Cute Unicorn coloring page Free Printable Coloring Pages from Kids will surely fall in love with this children's coloring page of a majestic unicorn. I love unicorns colouring printable with pegasus. ![]()
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7/6/2023 0 Comments Lemonade stand cool math games![]() Our DIY Lemonade Stand is the perfect project for a summer weekend. You’ll have the whole neighborhood lined up in no time! DIY Lemonade Stand Create a stand for your lemonade with this simple tutorial, then proudly display your artwork as you sell cups to neighbors, friends, friends on the street - anyone who wants to get a little refreshment going on. It's time for a lemonade break! Take advantage of that sunshine and make yourself a cool, refreshing glass of lemonade. Let your child paint the stand as they wish and add their own personal touch of flair. All you need are some pieces of wood, screws, and glue to build the base assembly of the stand, create upright support and hang the lemonade sign with it. This is the perfect project to turn your child into an entrepreneur. ![]() Make a lemonade stand with your child in a few easy steps. Top with a beautiful project panel top from The Home Depot, seal with stain, and add a clear protective coating. Cut and attach reclaimed wood pieces to the frame with glue and nails, then add a decorative bottom trim piece. Begin by making the base of the lemonade stand with 2x4s, project panel, and casters. This DIY rustic lemonade stand is easy to make and perfect for any summer season. Attach swivel casters to one side of the base so that you can easily move it around and cover the base with wooden boards cut into appropriate sizes. To start, assemble a square base for the lemonade stand by fitting four pieces of the board inside each other to hold them together. You will need the following materials: Plywood sheets, Wooden boards, Swivel casters, Fixed casters, Screws, and Glue. Learn how to build a DIY lemonade stand that can be constructed in a few easy steps. Then let him or her loose on the neighborhood. Motivate your child to think about how to decorate his stand, as well as what good cause it should support, such as an animal shelter or children's hospital. Spray paint the crates and attach wooden dowels to the sides with brackets. Just get four milk crates and join them together in two rows with the front of the crates alternating. If you are looking for a fun summer project for your little one, why not build your own lemonade stand? No woodworking skills are required. Finally, finish off the look with our floral wreath garland. Then, attach your wooden dowels to the sides of the crates so your little one can hang his or her favorite sign-up. Simply stack the crates up and paint the boards in alternating white and yellow colors. All you need are 2 big wooden crates, some paint, and a few other items. This DIY lemonade stand is fun and easy to make – anyone can do it. The downloadable plans include a complete parts list, cutting list, detailed Sketchup drawings, and step-by-step assembly instructions for a DIY project that's sure to keep your kids running their own little business for many years to come. This adorable little stand is built from plywood and can be completed in one afternoon. Welcome to the Lemonade Stand! The perfect place for pretend play or a summer lemonade stands at the end of the driveway. ![]() They are perfect for anyone who wants to make some quick cash at home! You won’t find these stands anywhere else because we made them ourselves using our ideas and materials. The best part about these DIY lemonade stands is that they’re all custom-made! Each one has its own unique design and color scheme. You will find everything from simple cardboard stands to full-blown wooden stands. We have gathered 24 DIY Lemonade Stand Ideas that are easy to make and will be fun for both you and your little ones. With that being said, below are the best DIY Lemonade Stand Ideas that you can build for your children or yourself! Lemonade stands are usually used during the summer because most people prefer to drink cold drinks than hot drinks when it’s hot outside. Why should get a lemonade stand? Lemonade stands help you to make some money or raise funds for some cause. They are used to sell lemonade, hence the name. Nowadays, lemonade stands are used by both kids and adults. ![]() ![]() The lemonade stand was also an opportunity for kids to have fun with friends and make money at the same time. It was one of the ways to learn about business and working for a living. In the olden days, every kid dreamt of building their own lemonade stand. ![]() ![]() ![]() ![]() Continued abuse of our services will cause your IP address to be blocked indefinitely. Please fill out the CAPTCHA below and then click the button to indicate that you agree to these terms. 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If you are using the Brave browser, or have installed the Ghostery add-on, these programs send extra traffic to our servers for every page on the site that you browse, then send that data back to a third party, essentially spying on your browsing habits.We strongly recommend you stop using this browser until this problem is corrected. The latest version of the Opera browser sends multiple invalid requests to our servers for every page you visit.The most common causes of this issue are: Your IP address has been temporarily blocked due to a large number of HTTP requests. ![]() ![]() There's so much depression and gravitas in a place like Brooklyn (and Manhattan) with so many transplants just frolicking in the middle of it. On the other hand, there's a much larger population of people in the background that just lost a minimum wage job, just buried a son, or just got their results back from an HIV test. On the one hand, there are people who do yoga exercises in the park, drop $5 on lattes and sit leisurely outside of coffeeshops and read Malcolm Gladwell. In my mind, it's not so much about the absolute numbers of gentrifiers as it is the sharp contrast you see between two different worlds. ![]() I'm glad my neighborhood still terrifies my out-of-town / suburban guests a little bit. For us oldtimers the place was just a new spot to get something to eat.ĭo recent transplants really hate bodegas? I love, love, love the Yucca Market in my neighborhood - you can get so much stuff you'd never be able to get at a Trader Joe's or Wholefoods.įrom what I have read / heard, it sounds like DC and NYC are two cities that are starting to get over-gentrified in a lot of places (in LA I can think of SM and Silverlake, maybe Los Feliz as being over-gentrified). Here in CH for example, a place like Choice on Lafayette, was looked at like a godsend to the hood if you let newer residents tell it. Please NO BODEGAS! Bodegas spell doom to some folks). Next they might let you know about a vacant storefront with a speculative wish list (like restaurants, organic markets, wine stores, coffee shoppes w/ WiFi, Korean convenient store, etc. or lack thereof, in which case they will note that the “nabe” is “up and coming”, then point out a few restaurants or a place where they get good expresso and check facebook work on their writing (Does everyone now get writing inspiration in coffee shops? Hmm). Ask a newer resident and you’ll likely to hear about “amenities” like restaurants, organic markets, wine stores, coffee shoppes w/ WiFi, Korean convenient store, etc. ![]() You will probably hear things like proximity to family, close bonds with friends and neighbors, communal interactions and places of worship. ![]() Ask a long-time resident about their neighborhood. ![]() 7/5/2023 0 Comments Free credits imvu![]() This subreddit is not endorsed by, directly affiliated with, maintained, authorized, sponsored, or in any way officially connected with IMVU Inc.
7/5/2023 0 Comments Kinematic viscosity![]() ![]() Sometimes, viscosity is erroneously referred to as thickness (or weight). Generally speaking, viscosity is a fluid’s resistance to flow (shear stress) at a given temperature. Given the importance of viscosity analysis coupled with the increasing popularity of onsite oil analysis instruments used to screen and supplement offsite laboratory oil analysis, it is essential that oil analysts understand the difference between dynamic and kinematic viscosity measurements. By contrast, most onsite viscometers measure dynamic viscosity, but are programmed to estimate and report kinematic viscosity, so that the viscosity measurements reported reflect kinematic numbers reported by most labs and lube oil suppliers. Most used oil analysis laboratories measure and report kinematic viscosity. The two are easily confused, but are significantly different. Viscosity can be measured and reported as dynamic (absolute) viscosity or as kinematic viscosity. However, there is more to viscosity than meets the eye. Likewise, there is no property more critical to effective component lubrication than base oil viscosity. Of all the tests employed for used oil analysis, none provides better test repeatability or consistency than viscosity. Viscosity reporting is only valid when the temperature at which the test was conducted also is reported - for example 23 cSt at 40 degrees C. This value is converted to standard units such as centistokes (cSt) or square millimeters per second. It is determined by measuring the time in seconds, required for a fixed volume of fluid to flow a known distance by gravity through a capillary within a calibrated viscometer at a closely controlled temperature. In the kinematic measuring method, gravity is the only force that acts on the sample.Kinematic viscosity is a measure of a fluid's internal resistance to flow under gravitational forces. The mass (or weight) of a fluid is determined by gravity. Therefore, we say that steel has a greater density than ice cube. ![]() They may be the same size, but the steel cube weighs more than the ice cube. Think about an ice cube and a cube of steel. Dynamic (cP) / Density = Kinematic (cSt)įor a given sample, with a density greater than one, dynamic viscosity will always be the higher number.ĭensity is the ratio of the mass (or weight) of the sample divided by the volume of the sample.Kinematic (cSt) x Density = Dynamic (cP).Density actually provides a way to convert between a kinematic and a dynamic viscosity measurement. The unit of measure of kinematic viscosity is Centistokes (cSt).Ī basic difference between the dynamic and kinematic viscosity measurements is density. The time is converted directly to kinematic viscosity using a calibration constant provided for the specific tube. There are several ways to find the kinematic viscosity of a fluid, but the most common method is determining the time it takes a fluid to flow through a capillary tube. Put another way, kinematic viscosity is the measure of a fluid’s inherent resistance to flow when no external force, except gravity, is acting on it. The other way is to measure the resistive flow of a fluid under the weight of gravity. One way is to measure a fluid’s resistance to flow when an external force is applied. ![]() Water at 20 ☌ has a kinematic viscosity of about 1 cSt. Other units are: 1 St ( Stoke) = 1 cm 2/s = 10 −4 m 2/s. The SI unit of the kinematic viscosity is m 2/s. The kinematic viscosity is the ratio between the dynamic viscosity and the density of a fluid. ![]() 7/5/2023 0 Comments Tekken 3 cheats xbox![]() ![]() Tekken 7 is an immersive 3D fighting game that tests a player’s reflex, skill and mental prowess within the environmental battlefield of game play. Note: While this download is restricted to Europe, Australia, New Zealand and the Middle East, you can make an extra account for the UK to download it to your PS4 harddrive, then switch back to your main PSN account, and this theme will be waiting for activation on your PS4’s harddrive. How To Unlock The Tekken 7 Dynamic Theme: Register an account on the official Bandai Namco European website, and then get a free download for this fully dynamic PS4 theme featuring the legendary feud of the Mishima Clan but also displaying Akuma from Street Fighter! It’s different from & better than the pre-order bonus theme. King’s second Rage Art can only be done when you have the 3 pieces of the “King & Kazuchika Okada” clothing equipped.Ī Rage Art can be performed when you get to low health, you can either do the combo which can be found in the moves list to perform it, or you can simply press R1 (on PS4) or RB (on Xbox One). How To Unlock The 2nd Rage Art for King: King is the only character who has two different Rage Arts finisher moves. When you drain his life, he will perform his Raging Demon super ‘Messatsu’ and you will need to execute your own Rage Art - R1 on PS4 / RB on Xbox One - to counter. If Akuma blocks, don’t use it more than 2 times, he will counter after 3 blocks.Ĥ. If the hit connects, keep pressing RP to chain the Basic Combo 2. It’s one of the fastest moves Kazuya has. Akuma will throw two hits which you can block and punish immediately with Devil Fist (forward, forward, RP). Use Devil Blaster (LK+RK) at long range or Reverse Devil Blaster when Akuma is mid-range.ģ. Set the difficulty on Easy so that you get Basic Combos.Ģ. ![]() Here’s a step-by-step cheat to beat Akuma:ġ. ![]() 7/5/2023 0 Comments Pocket protector![]() This condition occurs when the scar tissue around a breast implant becomes tight, sometimes causing deformity and pain. The agency has also established the Women’s Health Technologies Strategically Coordinated Registry Network to provide more complete evidence in clinical areas that are unique to women, such as uterine fibroids and pelvic floor disorders.Ĭapsular contracture is a known complication of breast implants. As part of the Medical Device Safety Action Plan and the agency’s ongoing commitment to advancing women’s health, the FDA has warned the public when safety issues are identified, such as breast implant-associated anaplastic large cell lymphoma, vaginal rejuvenation and unsafe silicone injections. The warning letter issued today reflects the agency’s commitment to advancing policies that enhance the FDA’s oversight of device safety, including device therapies unique to women. We’ll continue our efforts to protect patients from those individuals who choose to skirt laws intended to keep patients safe and sell unproven and potentially unsafe medical products.” Berman is taking advantage of patients and exposing them to a broad range of unknown health risks, including not effectively preventing capsular contracture as the product claims or causing additional harm such as infection or adverse reactions with the breast implant. By illegally manufacturing and marketing this device, Dr. Berman is well aware that the FDA has never approved any product to prevent or treat capsular contracture. Berman concerning his illegal marketing of unapproved medical products and potentially putting his patients at significant risk. “This is not the first time the FDA has notified Dr. ![]() As part of these efforts, we will not tolerate bad actors who take advantage of patients by marketing unapproved and potentially unsafe products that deceive patients and put them at risk,” said FDA Commissioner Scott Gottlieb, M.D. ![]() ![]() “Advancing and protecting women’s health is a priority for the FDA. Berman of significant deviations from the FDA’s quality system requirements and current good manufacturing practices (CGMPs), including deviations from manufacturing processes intended to keep implants sterile. Berman claims can prevent and treat a complication of breast implants known as capsular contracture, or tightening of scar tissue. Food and Drug Administration issued a warning letter to Mark Berman, M.D., of Beverly Hills, California, for illegally marketing an unapproved implantable device, the Pocket Protector, that Dr. ![]() ![]() Meanwhile, the stories about the Rhode Island farmhouse, which was at one point owned by the Perron family, is one the Perrons-especially daughter Andrea-have continually validated. On one side, you have the case files of Ed and Lorraine Warren, the demonologists about whom “The Conjuring” film series is based. The information surrounding the farm on Round Top Road is mired in myth, superstition, and anger. “The Sleepless Unrest: The Real Conjuring House” will screen in select theaters and be available on VOD starting July 16, 2021. Otherwise, “The Sleepless Unrest” is a clever paranormal documentary that delivers the chills and thrills. I am certain this qualm qualifies me as a buzzkill. This becomes awkward when their friend Brian finds a mysterious note folded in a book and says, “Wouldn’t it be crazy if I opened it and it said ‘Bathsheba’?” Sure, it is safe to assume anyone watching “The Sleepless Unrest” has seen “The Conjuring,” but without additional non-fictional context, the audience has no choice but to believe everything that happened in the fictional film was real. Still, because there is no direct mention of the home’s history, there is an assumption the audience already knows quite a bit about it. It was about a new chapter of this famous location.” So, this documentary wasn’t about setting straight or saying who’s wrong and who’s right. “We confirmed with the homeowners that, yes indeed there is a lot of misinformation. Vera suggested it was a means to maintain objectivity in the face of contradicting information. While the Whelptons are open about how the immediacy of the invitation did not give them much time to do proper research, it still leaves a mark on the film. ![]() Yet, there is a little disappointment to be had. Fans of the genre will not be disappointed. And musical sensors that get triggered in the middle of the night. There is also an attic space with a pentagram traced out on some ash. What separates this film from the rest of the pack is the warmth of our investigators and a few creepy moments, especially in the house’s basement where there just so happens to be a curious well. We get plenty of long, expectant takes scored with ominous tones. In some ways, “The Sleepless Unrest” is like an extended episode of “Ghost Hunters.” There is the camera set-up, the exploration, moments of fright at the unseen. Elation and trepidation stand out in equal measure. Everyone is bubbling over like a group of teenagers waiting in line to get into Halloween Horror Nights at Universal Studios. They also introduce us to the current owners of the farmhouse, Cory and Jennifer Heinzen. In horror movie tradition, we spend time upfront getting to know Kendall, Vera, and their friends, Brian and Richelle. Instead of a methodical introduction outlining the history of the haunted home, the Whelptons and their friends dive right into the pleasures of a group of people ecstatic to chase down ghosts at one of America’s most notable haunts. This spur of the moment excitement defines the film. “Basically, I don’t know if this has ever been done before, where you get a call and two weeks later you just jump in your car with your cameras and you’re just documenting everything.” Kendall-a cinematographer on the A&E “Ghost Hunters” series-and Vera, herself a paranormal investigator, were approached with a delicious offer: two weeks in the Rhode Island farmhouse that inspired the events of James Wan’s blockbuster 2013 horror film, “The Conjuring.” Owners Cory and Jennifer Heinzen stand outside the infamous ‘Conjuring’ farmhouse.ĭuring the height of the COVID-19 pandemic, Kendall and Vera were on a phone call with their friends, Brian and Richelle, when Brian floated an invitation to hang out together for a couple weeks at “The Conjuring” home. The origin of this film was surprisingly impromptu. By integrating some tried and true tricks with a less formulaic approach to the storytelling, the Whelptons have come across a fresh approach to the haunted house doc. ![]() ![]() “The Sleepless Unrest: The Real Conjuring House,” a horror documentary from Kendall and Vera Whelpton, unlocks new rooms in the paranormal investigation genre. ![]() “We knew we had something different going into this. ![]() 7/5/2023 0 Comments Entropy of vaporization![]() ![]() (b) Calculate the enthalpy of vaporization of methanol, assuming that rS doesnt depend on temperature and taking the boiling point of methanol to be 64.6C. (a) Calculate the entropy change for the vaporization of 1 mol methanol (use data from Table 16.1 or Appendix J). Once we get all the values of entropy change, just add them up to get the standard molar entropy of vaporization of water. The standard molar entropy of methanol vapor, CH3OH(g), is 239.8 J K1 mol-1. This was the best explanation for this problem! I just followed these steps and finally got the right answer :) What is the boiling point(C) of a liquid with entropy of vaporization 68.3 JK1mol1 and enthalpy of vaporization 35.65 kJ mol1: rounded up to two decimal. As the degree of the disorder increases in the transition, from a liquid having a small volume to a vapour having a larger volume, the entropy of vaporisation is always positive. ![]() Once we get all the values of entropy change, just add them up to get the standard molar entropy of vaporization of water. The entropy of vaporisation is the increase in entropy upon the vaporisation of a liquid. Just plug and solve to get that entropy change The entropy of vaporization at the normal boiling point has been estimated for binary and ternary azotropic mixtures containing water, alcohol or acetic. Only this time, we use the Cpm 33.6 J⋅K−1⋅mol−1 for water vapor and the temperature change is from 100 ☌ to 59 ☌. To solve the third part, we use again the equation ∆S = Cpm ln (T2/T1). Since the Cpm is 75.3 J⋅K−1⋅mol−1 for liquid water and the temperature change is from 59.0 ☌ to 100 ☌, just plug and solve to get the entropy changeĪs for the second part, we already are given the entropy of vaporization of water at 100 ☌ which is 109.0 J⋅K−1⋅mol−1. To solve the first part, we should use the equation ∆S = Cpm ln (T2/T1). Entropy of vaporization is an increase in entropy upon vaporization of a liquid.To solve this problem, we need to know three steps that involve finding the standard molar entropy of vaporization: the entropy change heating water from 59.0 ☌ to 100 ☌, the entropy of vaporization of water at 100.0 ☌, and the entropy change cooling water from 100 ☌ to 59 ☌. Note: Enthalpy of vaporization is the amount of energy that must be added to the liquid substance, to transform a quantity of that substance into gas. This maximum can be attained only in a completely reversible process. 1 atm.In thermodynamics, the Gibbs free energy is a thermodynamic potential that can be used to calculate the maximum of irreversible work that may be performed by a thermodynamic system at a constant temperature and pressure.The Gibbs free energy is the maximum amount of non-expansion work that can be extracted from a thermodynamic closed system. Std entropy change of fusion, fus S o 31 J/(mol·K) Std enthalpy change of vaporization, vap H o 42.3 ± 0. The change in free energy occurs when a compound is formed from its elements in their most thermodynamically stable state at standard state conditions i.e. Latent Heat of Vaporization are saturated properties, just enter One. ∴ Boiling point of the liquid at one atmospheric pressure is 400k. Pressure: Density: Volume: Quality: Internal Energy: Enthalpy: Entropy: Isochoric. ![]() ![]() $\Delta H$ = enthalpy of vaporization = 30000 $Jmo$ The entropy change for the system and its surroundings is identical in magnitude but opposite in direction, resulting in a zero entropy universe. It is given that Enthalpy of vaporization is 30 Kilojoules per mole. Entropies Equation of state Internal energies Isobars Isochores Isotherms Joule - Thomson inversion Latent heats of vaporization Melting. We know that at equilibrium, Gibbs energy change is zero. See Table 11.7 for heats of vaporization. vapor is in equilibrium at one atmospheric pressure. Calculate the change in entropy that occurs in the system when 1.00 mole of diethyl ether (C4H10O) condenses from. Hint: the fact that at boiling point of the liquid, liquid |